No. Wesker leaves Umbrella for The 3rd Organization in 1998 whom Ada is already working for. They are partnered together to get the G-Virus from Raccoon City. Interestingly, Wesker's Report 2 is addressed to Ada so it may be acting as a kind of 'CV' for his membership.
Sometime after Raccoon City, Ada leaves the 3rd Organization for 'another organization'.
Wesker stays with the 3rd Organization right through to the events of RE4 where he asks Ada to come and work for him. Ada's employers order her to join and then betray Wesker as a test of her loyalty to them, which she does.
Ada's unknown organization is not the 3rd Organization, and Ada Wong is not her real name. It is just the alias that both Leon and Wesker know her as, hence why she is called Ada once more during RE4.
Sometime after Raccoon City, Ada leaves the 3rd Organization for 'another organization'.
Wesker stays with the 3rd Organization right through to the events of RE4 where he asks Ada to come and work for him. Ada's employers order her to join and then betray Wesker as a test of her loyalty to them, which she does.
Ada's unknown organization is not the 3rd Organization, and Ada Wong is not her real name. It is just the alias that both Leon and Wesker know her as, hence why she is called Ada once more during RE4.
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